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Beilstein J. Org. Chem. 2012, 8, 528–533, doi:10.3762/bjoc.8.60
Graphical Abstract
Figure 1: Structure of depsipeptides szentiamide (1) [12] and xenematide (2) [8] identified in Xenorhabdus strains.
Scheme 1: Overview of the synthetic strategy.
Scheme 2: Synthesis of compound 1.
Figure 2: HPLC–MS data of an XAD-extract of X. szentirmaii (a; base-peak chromatogram), the natural 1 (b; ext...